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The New Jersey Institute of Technology's
Electronic Theses & Dissertations Project

Title: Esters of sulfanilic and substituted Sulfanilic acids
Author: Kovalsky, Stephen James
View Online: njit-etd1955-016
(35 pages ~ 1.1 MB pdf)
Department: Department of Chemical Engineering
Degree: Master of Science
Program: Chemical Engineering
Document Type: Thesis
Advisory Committee: Kreps, Saul I. (Committee chair)
Mantell, C. L. (Committee member)
Keeffe, George C. (Committee member)
Date: 1955-05
Keywords: Aniline
Availability: Unrestricted
Abstract:

Attempted esterification of p-acetaminobenezenesulfonyl chloride with any of the low molecular weight alcohols in aqueous systems always results in the formation of sulfanilic acid. When conducted in a non-aqueous medium, the desired esterification did not occur. A water soluble compound formed, instead, which has not yet been identified.

A study was made of sulfanilic acid esters. Alcoholysis reactions involving the butyl ester and methyl alcohol were successful only when the reaction was conducted under pressure and under anhydrous conditions.


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