Department of Chemical Engineering, Chemistry and Environmental Science
Degree:
Master of Science
Program:
Chemical Engineering
Document Type:
Thesis
Advisory Committee:
Knox, Dana E. (Committee chair)
Tomkins, R. P. T. (Committee member)
Petroulas, Theodore (Committee member)
Date:
1986-09
Keywords:
Equations of state
Availability:
Unrestricted
Abstract:
A general procedure for the development of density-dependent mixing rules is demonstrated. This method is used to obtain a density-dependent local-composition mixing rule based on an extention of the work of Knox et al (1984). The resulting expression is tested with the Soave-Redlich-Kwong equation of state. Results for normal and cryogenic vapor-liquid systems for both one-parameter and three-parameter versions of the mixing rule are compared with results using the classical mixing rules.
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