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The New Jersey Institute of Technology's
Electronic Theses & Dissertations Project

Title: Mass transfer into cylindrical liquid films measurement of liquid diffusivities
Author: Lovenguth, Ronald Francis
View Online: njit-etd1964-009
(vi, 37 pages ~ 2.0 MB pdf)
Department: Department of Chemical Engineering
Degree: Master of Science
Program: Chemical Engineering
Document Type: Thesis
Advisory Committee: Keeffe, George C. (Committee chair)
Salamone, Jerome J. (Committee member)
Joffe, Joseph (Committee member)
Date: 1964-05
Keywords: Diffusion
Liquids
Availability: Unrestricted
Abstract:

This thesis was undertaken to augment and validate the previous work of Ratcliff and Reid(7) in the area of diffusion of immiscible liquids. Their novel approach to this particular problem of liquid diffusion led the author to consider an experimental technique that has been used in gas-liquid studies. A short vetted-wall column was used to determine the rate of mass transfer of benzene and toluene into thin cylindrical films of water. A general analytical solution for the rate of mass transfer has been derived and is given below. This solution was checked using the system benzene-water.

G=3.63(Π(ρωβ)g/μl)1/6 R2/3 L1/2 D1/2AB Q1/3 CRo

The calculated diffusivity from the experimental results for the system benzene-water with the author's above derived equation gave a result which was approximately thirteen percent lower than that reported by Ratcliff and Reid(7) in their study of the same system using spherical films of water.

The system toluene-water was also studied and data is presented.


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